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.block-content-new-icon{height:7px;left:52px;position:absolute;top:3px}網(wǎng)頁新聞貼吧知道網(wǎng)盤圖片視頻地圖文庫資訊采購百科百度首頁登錄注冊進入詞條全站搜索幫助首頁秒懂百科特色百科知識專題加入百科百科團隊權威合作個人中心收藏查看我的收藏0有用+10GH4169播報討論上傳視頻沉淀強化鎳基高溫合金GH4169是一種沉淀強化鎳基高溫合金,在-253~650℃溫度范圍內(nèi)具有良好的綜合性能,650℃以下的屈服強度居變形高溫合金的首位,并具有良好的抗疲勞、抗輻射、抗氧化、耐腐蝕性能,以及良好的加工性能、焊接性能良好。能夠制造各種形狀復雜的零部件,在宇航、核能、石油工業(yè)及擠壓模具中,在上述溫度范圍內(nèi)獲得了極為廣泛的應用。外文名GH4169主要形式棒材、板材,帶材、管材主要用途航空發(fā)動機、核能工業(yè)、石油領域應用的零件特 點合金組織對熱加工工藝特別敏感制 造各種形狀復雜的零部件熔化溫度范圍1260~1320℃目錄1材料介紹?材料牌號?相近牌號?技術標準?化學成分?熱處理制度?規(guī)格與狀態(tài)?工藝?應用與要求2功能考核3物化性能?熱性能?密度?磁能型?化學性能4使用建議5性能要求?預熱?熱加工?冷加工?熱處理?打磨?機加工?焊接材料介紹播報編輯GH4169帶材樣件該合金的另一特點是合金組織對熱加工工藝特別敏感,掌握合金中相析出和溶解規(guī)律及組織與工藝、性能的相互關系,可針對不同的使用要求制定合理、可行的工藝規(guī)程,就能獲得可滿足不同強度級別和使用要求的各種零件。供應的品種有鍛件、鍛棒、軋棒、冷軋棒、圓餅、環(huán)件、板、帶、絲、管等??芍瞥杀P、環(huán)、葉片、軸、緊固件和彈性元件、板材結(jié)構(gòu)件、機匣等零部件在航空上長期使用。 [1]材料牌號GH4169GH169相近牌號Inconel718(美國),NC19FeNb法國技術標準GJB 2612-1996 《焊接用高溫合金冷拉絲材規(guī)范》HB 6702-1993 《WZ8系列用GH4169合金棒材》Q/6S 1034-1992 《高溫緊固件用GH4169合金棒材》Q/3B 548-1996 《GH4169合金鍛件》Q/3B 548-1996 《GH4169合金鍛件》Q/3B 4048-1993 《YZGH4169合金棒材》Q/3B 4050-1993 《GH4169合金板材》Q/3B 4051-1993 《GH4169合金絲材》GB/T14992-2005 《高溫合金》化學成分該合金的化學成分分為3類:標準成分、優(yōu)質(zhì)成分、高純成分,件表1-1。優(yōu)質(zhì)成分的在標準成分的基礎上降碳增鈮,從而減少碳化鈮的數(shù)量,減少疲勞源和增強強化相的數(shù)量,提高抗疲勞的含量,提高材料的純度和綜合性能。核能應用的GH4169合金,需控制硼的含量(其他元素成分不變),具體含量有工序雙方協(xié)商確定。當ω(B)≤0.002%時,為與宇航工業(yè)用的GH4169合金加以區(qū)別,合金牌號為GH4169A。表1-1類別CCrNiCoMoAlTiFe標準≤0.0817.0~21.050~55.0≤1.02.80~3.300.30~0.700.75~1.15余優(yōu)質(zhì)0.02~0.0617.0~21.050~55.0≤1.02.80~3.300.30~0.700.75~1.15余高純0.02~0.0617.0~21.050~55.0≤1.02.80~3.300.30~0.700.75~1.15余類別NbBMgMnSiPSCuCa--不大于不大于不大于不大于不大于不大于不大于不大于標準4.75~5.500.0060.010.350.350.0150.0150.300.01優(yōu)質(zhì)5.00~5.500.0060.010.350.350.0150.0150.300.01高純5.00~5.500.0060.0050.350.350.0150.0150.300.005類別BiSnPbAgSeTeTlNO-不大于不大于不大于不大于不大于不大于不大于不大于不大于標準------0.0005---0.0003------------優(yōu)質(zhì)0.0010.0050.0010.0010.0003------0.010.01高純0.000030.0050.0010.0010.00030.000050.00010.010.005熱處理制度合金具有不同的熱處理制度,以控制晶粒度、控制δ相形貌、分布和數(shù)量,從而獲得不同級別的力學性能。合金熱處理制度分3類:Ⅰ:(1010~1065)℃±10℃,1h,油冷、空冷或水冷+720℃±5℃,8h,以50℃/h爐冷至620℃±5℃,8h,空冷。經(jīng)此制度處理的材料晶粒粗化,晶界和晶內(nèi)均無δ相,存在缺口敏感性,但對提高沖擊性能和抵抗低溫氫脆有利。Ⅱ:(950~980)℃±10℃,1h,油冷、空冷或水冷+720℃±5℃,8h,以50℃/h爐冷至620℃±5℃,8h,空冷。Ⅲ:720℃±5℃,8h,以50℃/h爐冷至620℃±5℃,8h,空冷。經(jīng)此制度處理后,材料中的δ相較少,能提高材料的強度和沖擊性能。該制度也稱為直接時效熱處理制度。規(guī)格與狀態(tài)可供應模鍛件(盤、盤整體鍛件)、餅、環(huán)、棒(鍛棒、軋棒、冷拉棒)、板、絲、帶、管、不同形狀和尺寸的緊固件、彈性元件等。交貨狀態(tài)有供需雙方商定。絲材以商定的交貨狀態(tài)成盤裝交貨。工藝合金的冶煉工藝分為3類:真空感應電渣重熔;真空感應加真空電弧重熔;真空感應加電渣重熔加真空電弧重熔??筛鶕?jù)零件的使用要求,選擇所需的冶煉工藝,滿足應用要求。應用與要求制造航空和航天發(fā)動機中各種靜止件和轉(zhuǎn)動件,如盤、環(huán)件、機匣、軸、葉片、緊固件、彈性元件、燃氣導管、密封元件等和焊接結(jié)構(gòu)件;制造核能工業(yè)應用的各種彈性元件和格架;制造石油和化工領域應用的零件及其他零件。近年來,在對該合金研究不斷深化和對該合金應用不斷擴大的基礎上,為提高質(zhì)量和降低成本,發(fā)展了很多工藝:真空電弧重熔時采用氦氣冷卻工藝,有效的減輕鈮偏析;采用噴射成形工藝生產(chǎn)環(huán)件,降低成本和縮短生產(chǎn)周期;采用超塑成形工藝,擴大產(chǎn)品的生產(chǎn)范圍。功能考核播報編輯用該合金制造的渦輪盤、甩油盤、整體轉(zhuǎn)子、軸、緊固件等零件已按照發(fā)動機所用的型號規(guī)范,在發(fā)動機零、部件試驗中通過了超轉(zhuǎn)、破裂、低循環(huán)疲勞試驗;通過了高空臺試車個長期(壽命)試車及試飛發(fā)射的考核,達到了設計和應用的要求。物化性能播報編輯熱性能2.1.1 GH4169 熔化溫度范圍1260~1320℃2.1.2 GH4169 導熱率見表2-1表2-1θ/℃111002003004005006007008009001000λ/(W/(m·C))13.414.715.717.818.319.621.222.823.627.630.42.1.3 GH4169 比熱容見表2-2。表2-2θ/℃3004005006007008009001000c/(J/(kg·C))481.4493.9514.8539.0573.4615.3657.2707.42.1.4 GH4169 線膨脹系數(shù)見表2-3。表2-3θ/℃20~10020~20020~30020~40020~50020~60020~70020~80020~90020~1000α/10-6C-111.813.013.514.114.414.815.417.018.418.7密度ρ=8.24g/cm3磁能型合金無磁性化學性能2.5.1 GH4169 抗氧化性能在空氣介質(zhì)中試驗100h后的氧化速率見表2-4表2-4θ/℃6007008009001000氧化速率/(g/(m3·h))0.01760.02770.03510.09610.1620使用建議播報編輯推薦使用,使用中必須避免出現(xiàn)超過材料承受性能的應力集中。性能要求播報編輯3.1 GH4169性能3.1.1因GH4169合金中鈮含量高,合金中的鈮偏析成份都與冶金工藝直接相關。電渣重熔和真空電弧熔煉的熔煉速度和電極棒的質(zhì)量狀態(tài)直接影響材質(zhì)的優(yōu)劣。熔速快,易形成富鈮的黑斑;熔速慢,會形成貧鈮的白斑;電極棒表面質(zhì)量差和電極棒內(nèi)部有裂紋,均易導致白斑的形成,所以,提高電極棒質(zhì)量和控制熔速及提高鋼錠的凝固速率是冶煉工藝的關鍵因素。為避免鋼錠中的元素偏析過重,采用的鋼錠直徑不大于508mm。品均化工藝必須確保鋼錠中的L相完全溶解。鋼錠兩階段均勻化和中間坯二次均勻化處理的時間,根據(jù)鋼錠和中間坯的直徑而定。均勻化工藝的控制與材料中鈮的偏析程度直接相關。生產(chǎn)中采用的1160℃,20h+1180℃,44h的均勻化工藝,尚不足以消除鋼錠中心的偏析,因此建議采用以下工藝:1.1150℃~1160℃,20h~30h+1180℃~1190℃,110h~130h;2.1160℃,24h+1200℃,70h。3.1.2 經(jīng)均勻化處理的合金具有良好的熱加工性能。鋼錠的開坯加熱溫度不得超過1120℃。鍛件的鍛造工藝應根據(jù)鍛件使用狀況和應用要求,結(jié)合生產(chǎn)廠的條件而定。開坯和生產(chǎn)鍛件時,中間退火溫度和終端溫度必須根據(jù)零件所需要的組織狀態(tài)和性能來確定,一般情況下,鍛造的終端溫度控制在930℃~950℃之間為宜。各類鍛件的鍛造溫度和變形程度見表5-1表3-1鍛件類別第一次鍛造第一次鍛造第二次鍛造第二次鍛造晶粒度/級晶粒度/級-加熱溫度/℃變形量/%加熱溫度/℃變形量/%基本晶粒個別大晶粒普通1065~1090---1040~1065---4~6允許高強1040~1065---1010~104030~508≥2直接時效995~1025>50970~995>5010≥2預熱工件在加熱之前和加熱過程中都必須進行表面清理,保持表面清潔。若加熱環(huán)境含有硫、磷、鉛或其他低熔點金屬,GH4169合金將變脆。雜質(zhì)來源于做標記的油漆、粉筆、潤滑油、水、燃料等。燃料的硫含量要低,如液化氣和天然氣的雜質(zhì)含量要低于0.1%,城市煤氣的硫含量要低于0.25g/m3,石油氣的硫含量低于0.5%是理想的。加熱的電爐最好要具有較精確的控溫能力,爐氣必須為中性或弱堿性,應避免爐氣成分在氧化性和還原性中波動。熱加工GH4169合金合適的熱加工溫度為1120-900℃,冷卻方式可以是水淬或其他快速冷卻方式,熱加工后應及時退火以保證得到最佳的性能。熱加工時材料應加熱到加工溫度的上限,為了保證加工時的塑性,變形量達到20%時的終加工溫度不應低于960℃。冷加工冷加工應在固溶處理后進行,GH4169的加工硬化率大于奧氏體不銹鋼,因此加工設備應作相應調(diào)整,并且在冷加工過程中應有中間退火過程。熱處理不同的固溶處理和時效處理工藝會得到不同的材料性能。由于γ”相的擴散速率較低,所以通過長時間的時效處理能使GH4169合金獲得最佳的機械性能。打磨在GH4169工件焊縫附近的氧化物要比不銹鋼的更難以去除,需要用細砂帶打磨,在硝酸和氫氟酸的混合酸中酸洗之前,也要用砂紙去除氧化物或進行鹽浴預處理。機加工GH4169的機加工需在固溶處理后進行,要考慮到材料的加工硬化性,與奧氏體不銹鋼不同的是, GH4169適合采用低表面切削速度。焊接沉淀硬化型的GH4169合金很適合于焊接,無焊后開裂傾向。適焊性、易加工性、高強度是這種材料的幾大優(yōu)點。GH4169適合于電弧焊、等離子焊等。在焊接前,材料表面要潔凈、無油污、無粉筆記號等,焊縫周圍25mm 范圍內(nèi)要打磨露出光亮的金屬。GH4169 推薦使用的焊接材料:GTAW/GMAWNicrofer S 5219W.-Nr. 2.4667SG-NiCr19NbMoTiAWS A 5.14 ERNiFeCr-2BS 2901 Part 5: NA 51新手上路成長任務編輯入門編輯規(guī)則本人編輯我有疑問內(nèi)容質(zhì)疑在線客服官方貼吧意見反饋投訴建議舉報不良信息未通過詞條申訴投訴侵權信息封禁查詢與解封?2025?Baidu?使用百度前必讀?|?百科協(xié)議?|?隱私政策?|?百度百科合作平臺?|?京ICP證030173號?京公網(wǎng)安備11000002000001號window.PAGE_DATA= 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GH4169(GH169) 一、GH4169 概述 GH4169合金是以體心四方的γ"和面心立方的γ′相沉淀強化的鎳基高溫合金,在-253~700℃溫度范圍內(nèi)具有良好的綜合性能,650℃以 下的屈服強度居變形高溫合金的首位,并具有良好的抗疲勞、抗輻射、抗氧化、耐腐蝕性能,以及良好的加工性能、焊接性能和長期組織穩(wěn)定性,能夠制造各種形狀 復雜的零部件,在宇航、核能、石油工業(yè)中,在上述溫度范圍內(nèi)獲得了極為廣泛的應用。 該合金的另一特點是合金組織對熱加工工藝特別敏感,掌握合金中相析出和溶解規(guī)律及組織與工藝、性能間的相互關系,可針對不同的使用要求制定合理、 可行的工藝規(guī)程,就能獲得可滿足不同強度級別和使用要求的各種零件。供應的品種有鍛件、鍛棒、軋棒、冷軋棒、圓餅、環(huán)件、板、帶、絲、管等??芍瞥杀P、 環(huán)、葉片、軸、緊固件和彈性元件、板材結(jié)構(gòu)件、機匣等零部件在航空上長期使用。 1.1 GH4169 材料牌號 GH4169(GH169)1.2 GH4169 相近牌號 Inconel 718(美國),NC19FeNb(法 國)1.3 GH4169 材料的技術標準GJB 2612-1996 《焊接用高溫合金冷拉絲材規(guī)范》HB 6702-1993 《WZ8系列用GH4169合金棒材》GJB 3165 《航空承力件用高溫合金熱軋和鍛制棒材規(guī)范》GJB 1952 《航空用高溫合金冷軋薄板規(guī)范》GJB 1953《 航空發(fā)動機轉(zhuǎn)動件用高溫合金熱軋棒材規(guī)范》GJB 2612 《焊接用高溫合金冷拉絲材規(guī)范》GJB 3317《 航空用高溫合金熱軋板材規(guī)范》GJB 2297 《航空用高溫合金冷拔(軋)無縫管規(guī)范》GJB 3020 《航空用高溫合金環(huán)坯規(guī)范》GJB 3167 《冷鐓用高溫合金冷拉絲材規(guī)范》GJB 3318 《航空用高溫合金冷軋帶材規(guī)范》GJB 2611《 航空用高溫合金冷拉棒材規(guī)范》YB/T5247 《焊接用高溫合金冷拉絲》YB/T5249 《冷鐓用高溫合金冷拉絲》YB/T5245 《普通承力件用高溫合金熱軋和鍛制棒材》GB/T14993《 轉(zhuǎn)動部件用高溫合金熱軋棒材》GB/T14994 《高溫合金冷拉棒材》GB/T14995 《高溫合金熱軋板》GB/T14996 《高溫合金冷軋薄板》GB/T14997 《高溫合金鍛制圓餅》GB/T14998 《高溫合金坯件毛壞》GB/T14992 《高溫合金和金屬間化合物高溫材料的分類和牌號》HB 5199《 航空用高溫合金冷軋薄板》HB 5198 《航空葉片用變形高溫合金棒材》HB 5189 《航空葉片用變形高溫合金棒材》HB 6072 《WZ8系列用GH4169合金棒材》1.4 GH4169 化學成分 該合金的化學成分分為3類:標準成分、優(yōu)質(zhì)成分、高純成分,見表1-1。優(yōu)質(zhì)成分的在標準成分的基礎上降碳增鈮,從而 減少碳化鈮的數(shù)量,減少疲勞源和增加強化相的數(shù)量,提高抗疲勞性能和材料強度。同時減少有害雜質(zhì)和氣體含量。高純成分是在優(yōu)質(zhì)標準基礎上降低硫和有害雜質(zhì) 的含量,提高材料純度和綜合性能。核能應用的GH4169合金,需控制硼含量(其他元素成分不變),具體含量由供需雙方協(xié)商確定。當ω(B)≤0.002%時,為與宇航工業(yè)用的GH4169合金加以區(qū)別,合金牌號為GH4169A。表1-1[1] %類別C Cr Ni Co Mo Al Ti Fe標準≤0.08 17.0~21.0 50.0~55.0 ≤1.02.80~3.30 0.30~0.70 0.75~1.15 余優(yōu)質(zhì)0.02~0.06 17.0~21.0 50.0~55.0 ≤1.0 2.80~3.30 0.30~0.70 0.75~1.15 余高純0.02~0.06 17.0~21.0 50.0~55.0 ≤1.0 2.80~3.30 0.30~0.70 0.75~1.15 余類別NbB Mg Mn Si P S CuCa不大于標準4.75~5.500.0060.010.350.350.0150.0150.300.01優(yōu)質(zhì)5.00~5.500.006 0.010.350.350.0150.0150.300.01高純5.00~5.500.0060.0050.350.350.0150.0020.300.005續(xù)表1-1 %類別BiSnPbAg SeTeTlN O不大于標準------0.0005---0.0003